Anglesite (PbSO4) epitactic overgrowths and substrate-induced twinning on anhydrite (CaSO4) cleavage surfaces
نویسندگان
چکیده
منابع مشابه
Irreversible modifications of the porous microstructure of soluble anhydrite β-CaSO4 induced by hydration-dehydration cycles
The internal surface area of hexagonal (soluble) primary anhydrite CaSO4 produced by dehydration of gypsum decreases by about 70 % when the anhydrite is successively subjected to rehydration and dehydration at room temperature in humid air and in vacuum respectively. In the rehydration step, the hemihydrate is formed; its dehydration yields secondary anhydrite. Additional hydration-dehydration ...
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Anhydrite solubility in H2O–NaCl solutions was measured at 6–14 kbar, 600–800 C and NaCl mole fractions (XNaCl) of 0–0 3 in piston–cylinder apparatus. Solubilities were determined by weight changes of natural anhydrite in perforated Pt envelopes confined with fluid in larger Pt capsules. In initially pure H2O at 10 kbar and 800 C, CaSO4 concentration is low (0 03molal), though much larger than ...
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High-pressure Raman spectroscopic experiments of anglesite, PbSO4, were carried out in a diamond anvil cell up to about 35 GPa at room temperature. Two stages of changes in the pattern of wavenumber-versus-pressure plot were observed in most of the vibrational modes. The first stage of change is the kink in the slope of wavenumber-versus-pressure plot at about 14 GPa, indicating a change in the...
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Discovery of abundant anhydrite (CaS04) and gypsum (CaS0+2HzO) in the otherwise carbonate sediments comprising the upper portion of the rocks contained within the Chicxulub impact crater has prompted research on the shock-induced vaporization of these minerals. We use a vaporization criterion determined by shock-induced entropy. We reanalyze the shock wave experiments of Yang [ 11. He shocked 3...
متن کاملINITIATION OF CaSO4 SCALE FORMATION ON HEAT TRANSFER SURFACES UNDER POOL BOILING CONDITIONS
The success of innovative fouling mitigation techniques such as ion implantation depends upon early stage of scale formation on heat transfer surface. This is because the first crystalline nuclei that appear on the surface during the initial period dictate how fouling would develop in latter stages. In this study, the initial period of deposition of calcium sulphate on heat transfer surfaces ha...
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ژورنال
عنوان ژورنال: Journal of Crystal Growth
سال: 2013
ISSN: 0022-0248
DOI: 10.1016/j.jcrysgro.2013.06.010